Diagramas de Tanabe - Sugano

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d2 Tanabe-Sugano Diagram
∆o/B
E/
B
0
10
20
30
40
50
60
70
80
0 10 20 30 40
3A2g
3T 1g
3T 1g
1A1g
1T 2g
1T 1g
1E g
3T 2g
1T 2g
1A1g 1E g
3F
1D
3P
1G
1S
d3 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50
∆o/B
E/
B
4T 2g
4A2g
2T 2g
2E g
2A1g
2T 1g
4T 1g
4T 1g 2A2g
4F
4P
2G
2F
d4 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50
∆o/B
E/
B
3A1g
3T 1g
3T 2g
5E g
5T 2g
1A1g
1T 1g
3A2g 1A2g
5D
3H
3F , 3G
3D, 1I
1F
3P
1E g
1T 2g
1A2g
3A2g
3E g
5E g
3T 1g
d5 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50
∆o/B
E/
B
2E g
2T 2g
2A2g, 2T 1g
4A1g
4T 1g
2A1g
4T 1g4A2g
4T 2g
6A1g
6S
4G
2I
4F
4D
6A1g
2T 2g
d6 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50
∆o/B
E/
B
1T 1g
1A1g
1E g
3T 1g
5T 2g
3T 2g
3T 2g
5D
1F
3P
3H
5T2g
1A1g
3F , 3G
1G , 1I
1T 2g
3A2g
1A1g3A2g
1A2g
5E g3A2g
d7 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40 50
∆o/B
E/
B
2T 2g
4T 2g
4T 1g
2T 2g
4F
2G
2F
4P
4A2g2A2g 2A1g4T 1g
2T 1g
4T 1g
d8 Tanabe-Sugano Diagram
0
10
20
30
40
50
60
70
80
0 10 20 30 40
∆o/B
E/
B
3A2g
1T 1g
1A1g
3T 1g
3F
1G
1D
3T 2g
1T 2g1A1g 3T 1g
1T 2g
1E g3P
1S
1E g
d2 ν2/ν1 Ratio
ν 2
/ν
1
1.2
1.4
1.6
1.8
2.0
2.2
2.4
2.6
10 15 20 25 30 35 40
∆/B
d3 ν2/ν1 Ratio
1.2
1.3
1.4
1.5
1.6
1.7
1.8
0 10 20 30 40 50
∆o/B
ν 2
/ν
1
d8 ν2/ν1 Ratio
1.2
1.3
1.4
1.5
1.6
1.7
1.8
0 5 10 15 20 25 30 35 40
∆o/B
ν 2
/ν
1